Crystal Structure of Binuclear Cobalt Complexes [(Cp′′′Co)2(μ2-η1:η2-S2)2] and [(Cp′′′Co)2(μ2-η1:η2-Se2)2]

Аннотация

Binuclear cobalt complexes [(Cp′′′Co)₂(μ₂-η¹:η²-S₂)₂] (1) (Cp′′′ = η⁵-1,2,4-tris(tert-butyl)cyclopentadienide) and [(Cp′′′Co)₂(μ₂-η¹:η²-Se₂)₂] (2) are obtained by the interaction of [(Cp′′′Co)₂(μ-η⁴:η⁴-C₇H₈)] with excess sulfur or selenium respectively. The structures of the complexes are determined by single crystal X-ray diffraction.