The Atomic Structure of Cu(II) Acetate-Bipyridine Under Thermal Decomposition: An X-Ray Spectroscopy Study


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Abstract

A number of experimental techniques were used to study the changes in the atomic structure of copper(II) acetate-bipyridine under thermal decomposition between 25°C and 700°C to form copper-containing nanoparticles. The dynamics of structural changes during decomposition in a thermogravimetric chamber is compared with X-ray absorption spectra, IR spectra, and diffraction patterns for a sequence of annealing temperatures. The experimental results were used to construct theoretical structural models of the complex under thermal decomposition.

About the authors

M. A. Kremennaya

The Smart Materials Research Center

Author for correspondence.
Email: kremennayamariya@gmail.com
Russian Federation, Rostov-on-Don

A. P. Budnyk

The Smart Materials Research Center

Email: kremennayamariya@gmail.com
Russian Federation, Rostov-on-Don

M. A. Soldatov

The Smart Materials Research Center

Email: kremennayamariya@gmail.com
Russian Federation, Rostov-on-Don

T. A. Lastovina

The Smart Materials Research Center

Email: kremennayamariya@gmail.com
Russian Federation, Rostov-on-Don

A. V. Soldatov

The Smart Materials Research Center

Email: kremennayamariya@gmail.com
Russian Federation, Rostov-on-Don

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