Synthesis of preceramic organomagnesiumoxanealumoxanes


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Preceramic organomagnesiumoxanealumoxanes hydrolytically stable in air and soluble in organic solvents, exhibiting fiber-forming properties at Al: Mg molar ratios of 2: 1 and 1: 1, have been synthesized for the first time. The physicochemical properties of the organomagnesiumoxanealumoxanes and ceramic samples prepared from them have been studied by a variety of techniques (nuclear magnetic resonance, IR spectroscopy, scanning electron microscopy, thermogravimetric analysis, X-ray diffraction, and elemental analysis).

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G. Shcherbakova

State Research Institute for Chemistry and Technology of Organoelement Compounds

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Email: eos2004@inbox.ru
俄罗斯联邦, sh. Entuziastov 38, Moscow, 105118

P. Storozhenko

State Research Institute for Chemistry and Technology of Organoelement Compounds

Email: eos2004@inbox.ru
俄罗斯联邦, sh. Entuziastov 38, Moscow, 105118

N. Krivtsova

State Research Institute for Chemistry and Technology of Organoelement Compounds

Email: eos2004@inbox.ru
俄罗斯联邦, sh. Entuziastov 38, Moscow, 105118

N. Kutinova

State Research Institute for Chemistry and Technology of Organoelement Compounds

Email: eos2004@inbox.ru
俄罗斯联邦, sh. Entuziastov 38, Moscow, 105118

T. Apukhtina

State Research Institute for Chemistry and Technology of Organoelement Compounds

Email: eos2004@inbox.ru
俄罗斯联邦, sh. Entuziastov 38, Moscow, 105118

M. Varfolomeev

State Research Institute for Chemistry and Technology of Organoelement Compounds

Email: eos2004@inbox.ru
俄罗斯联邦, sh. Entuziastov 38, Moscow, 105118

M. Kuznetsova

State Research Institute for Chemistry and Technology of Organoelement Compounds

Email: eos2004@inbox.ru
俄罗斯联邦, sh. Entuziastov 38, Moscow, 105118

A. Drachev

State Research Institute for Chemistry and Technology of Organoelement Compounds

Email: eos2004@inbox.ru
俄罗斯联邦, sh. Entuziastov 38, Moscow, 105118

I. Stolyarova

State Research Institute for Chemistry and Technology of Organoelement Compounds

Email: eos2004@inbox.ru
俄罗斯联邦, sh. Entuziastov 38, Moscow, 105118

A. Ashmarin

Baikov Institute of Metallurgy and Materials Science

Email: eos2004@inbox.ru
俄罗斯联邦, Leninskii pr. 49, Moscow, 119991

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