Effect of metal compounds on α-Si3N4 formation during silicon combustion in nitrogen in the presence of organic additives


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We have examined the effect of metal compounds on α-Si3N4 formation as a result of silicon combustion in nitrogen in the presence of organic compounds. The results demonstrate that the iron and copper chlorides FeCl3 · 6Н2О and CuCl2 · 2Н2О have the strongest effect on α-Si3N4 formation. The contributions of the metal chlorides and organic compounds to α-Si3N4 formation have been shown to be nonadditive.

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T. Barinova

Institute of Structural Macrokinetics and Materials Science

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Email: tbarinova@ism.ac.ru
俄罗斯联邦, ul. Akademika Osip’yana 8, Chernogolovka, Moscow oblast, 142432

I. Borovinskaya

Institute of Structural Macrokinetics and Materials Science

Email: tbarinova@ism.ac.ru
俄罗斯联邦, ul. Akademika Osip’yana 8, Chernogolovka, Moscow oblast, 142432

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