Coprecipitation of tellurium(IV), tungsten(VI), and lanthanum(III) hydroxides from aqueous solutions


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We have investigated the coprecipitation of tellurium(IV), tungsten(VI), and lanthanum(III) hydroxides through the addition of aqueous ammonia to a mixture of tellurium dioxide, lanthanum oxide, and tungstic acid solutions in hydrochloric acid. The effects of initial solution composition and precipitation pH on the composition of the precipitate have been assessed. It has been shown that the composition of the precipitate is essentially identical to that of the starting solution if the relative contents of lanthanum and tungsten in the mixture are within 20 mol % and precipitation is ceased at pH 7.

作者简介

A. Sibirkin

Lobachevsky State University; Devyatykh Institute of Chemistry of High-Purity Substances

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Email: inorgnngu@rambler.ru
俄罗斯联邦, pr. Gagarina 23, Nizhny Novgorod, 603950; ul. Tropinina 49, Nizhny Novgorod, 603950

S. Gavrin

Lobachevsky State University

Email: inorgnngu@rambler.ru
俄罗斯联邦, pr. Gagarina 23, Nizhny Novgorod, 603950

A. Suchkov

Devyatykh Institute of Chemistry of High-Purity Substances

Email: inorgnngu@rambler.ru
俄罗斯联邦, ul. Tropinina 49, Nizhny Novgorod, 603950

O. Zamyatin

Lobachevsky State University

Email: inorgnngu@rambler.ru
俄罗斯联邦, pr. Gagarina 23, Nizhny Novgorod, 603950

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