Local crystal structure of multiferroic BiMnO3 studied by 57Fe probe Mössbauer spectroscopy


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This paper presents a 57Fe probe Mössbauer spectroscopy study of a BiMn0.9657Fe0.04O3 manganite synthesized at high pressure (6 GPa). The BiMnO3 manganite possesses multiferroic properties and exhibits cooperative orbital ordering due to Jahn–Teller active Mn3+ ions. 57Fe Mössbauer spectra have been measured and analyzed in a wide temperature range, which includes the orbital ordering temperature of BiMnO3.

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Ya. Glazkova

Faculty of Chemistry

编辑信件的主要联系方式.
Email: janglaz@bk.ru
俄罗斯联邦, Moscow, 119899

A. Belik

National Institute for Materials Science

Email: janglaz@bk.ru
日本, 1-2-1 Sengen, Tsukuba, Ibaraki, 305-0047

A. Sobolev

Faculty of Chemistry

Email: janglaz@bk.ru
俄罗斯联邦, Moscow, 119899

I. Presniakov

Faculty of Chemistry

Email: janglaz@bk.ru
俄罗斯联邦, Moscow, 119899

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