Thermally Controlled Formation of WO3 Nano- and Microcrystals on the Surface of Coatings Produced on Titanium by Plasma Electrolytic Oxidation


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We demonstrate that air annealing of oxide layers produced on titanium by plasma electrolytic oxidation and containing WO3, MnWO4, and ZnWO4 leads to the surface growth of nano- and microcrystals consisting predominantly of WO3. The crystals are initially formed around the perimeter of the coating pores. The size, composition, and number of crystals depend on the annealing temperature. We discuss possible causes and mechanisms of crystal growth.

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V. Rudnev

Institute of Chemistry, Far East Branch, Russian Academy of Sciences; Far East Federal University

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Email: rudnevvs@ich.dvo.ru
俄罗斯联邦, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022; ul. Sukhanova 8, Vladivostok, 690091

M. Vasilyeva

Institute of Chemistry, Far East Branch, Russian Academy of Sciences; Far East Federal University

Email: rudnevvs@ich.dvo.ru
俄罗斯联邦, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022; ul. Sukhanova 8, Vladivostok, 690091

I. Lukiyanchuk

Institute of Chemistry, Far East Branch, Russian Academy of Sciences

Email: rudnevvs@ich.dvo.ru
俄罗斯联邦, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022

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