Correlation between Refractive Index Dispersion Parameters and Cation Coordination Numbers in Fluoride Crystals


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Refractive index dispersion parameters of optical crystals of MFn (Mn+ = Na+, K+, Ca2+, Sr2+, Ba2+, Cd2+, Pb2+, La3+, Ce3+, Pr3+, Nd3+) binary fluorides have been shown to correlate with the cation coordination numbers in their structures. Using this correlation, I have demonstrated that, with increasing LaF3 concentration, the cation coordination number in Sr1 −xLaxF2 +x ternary fluoride crystals (fluorite structure) increases from 8 to 11.

Sobre autores

N. Sorokin

Shubnikov Institute of Crystallography, Crystallography and Photonics Federal Scientific Research Centre,
Russian Academy of Sciences

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Email: nsorokin1@yandex.ru
Rússia, Leninskii pr. 59, Moscow, 119333

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