Stabilization of the α-YF3 structure type by isomorphous substitutions


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The incorporation of manganese difluoride as a heterovalent additive into an α-(Yb1–yScy)F3 solid solution has made it possible to stabilize a solid solution with the α-YF3 (α-UO3) structure. The 573-K ionic conductivity of Yb0.49Sc0.26Mn0.25F2.75 is σ = 3 × 10–5 S/cm, with an activation enthalpy for ion transport ΔHσ = 0.6 eV (523–767 K).

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P. Fedorov

Prokhorov General Physics Institute

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Email: ppfedorov@yandex.ru
俄罗斯联邦, ul. Vavilova 38, Moscow, 119991

N. Sorokin

Shubnikov Institute of Crystallography, Crystallography and Photonics Federal Research Center

Email: ppfedorov@yandex.ru
俄罗斯联邦, Leninskii pr. 59, Moscow, 119333

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