Heat Capacity of the Gd2Ti2O7 and Lu2Ti2O7 Pyrochlores in the Range 350–1000 K


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The Gd2Ti2O7 and Lu2Ti2O7 titanates (pyrochlore structure, sp. gr. Fd3m) have been prepared by solid-state reactions in air at temperatures from 1673 to 1773 K using the Gd2O3, Lu2O3, and TiO2 oxides as starting materials. Their high-temperature heat capacity has been determined by differential scanning calorimetry in the range 350–1000 K. The experimental heat capacity data have been used to evaluate the thermodynamic functions of gadolinium and lutetium dititanates.

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L. Denisova

Institute of Nonferrous Metals and Materials Science, Siberian Federal University

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Email: antluba@mail.ru
俄罗斯联邦, Svobodnyi pr. 79, Krasnoyarsk, 660041

L. Chumilina

Institute of Nonferrous Metals and Materials Science, Siberian Federal University

Email: antluba@mail.ru
俄罗斯联邦, Svobodnyi pr. 79, Krasnoyarsk, 660041

V. Ryabov

Institute of Metallurgy, Ural Branch, Russian Academy of Sciences

Email: antluba@mail.ru
俄罗斯联邦, ul. Amundsena 101, Yekaterinburg, 620016

Yu. Kargin

Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences

Email: antluba@mail.ru
俄罗斯联邦, Leninskii pr. 49, Moscow, 119991

N. Belousova

Institute of Nonferrous Metals and Materials Science, Siberian Federal University

Email: antluba@mail.ru
俄罗斯联邦, Svobodnyi pr. 79, Krasnoyarsk, 660041

V. Denisov

Institute of Nonferrous Metals and Materials Science, Siberian Federal University

Email: antluba@mail.ru
俄罗斯联邦, Svobodnyi pr. 79, Krasnoyarsk, 660041

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