High-Temperature Heat Capacity and Thermodynamic Properties of HoBiGeO5 and ErBiGeO5
- Autores: Denisova L.T.1, Kargin Y.F.2, Belousova N.V.1, Galiakhmetova N.A.1, Denisov V.M.1
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Afiliações:
- Institute of Nonferrous Metals and Materials Science
- Baikov Institute of Metallurgy and Materials Science
- Edição: Volume 54, Nº 9 (2018)
- Páginas: 920-924
- Seção: Article
- URL: https://journals.rcsi.science/0020-1685/article/view/158524
- DOI: https://doi.org/10.1134/S0020168518090029
- ID: 158524
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Resumo
Polycrystalline HoBiGeO5 and ErBiGeO5 samples have been prepared by solid-state reactions, by firing stoichiometric mixtures of Ho2O3 (Er2O3), Bi2O3, and GeO2. The effect of temperature on the heat capacity of the synthesized compounds has been investigated by differential scanning calorimetry in the range 350–1000 K. The experimental Cp(T) data have been used to evaluate the thermodynamic functions of bismuth holmium and bismuth erbium germanates: enthalpy increment, entropy change, and reduced Gibbs energy.
Sobre autores
L. Denisova
Institute of Nonferrous Metals and Materials Science
Autor responsável pela correspondência
Email: antluba@mail.ru
Rússia, Svobodnyi pr. 79, Krasnoyarsk, 660041
Yu. Kargin
Baikov Institute of Metallurgy and Materials Science
Email: antluba@mail.ru
Rússia, Leninskii pr. 49, Moscow, 119991
N. Belousova
Institute of Nonferrous Metals and Materials Science
Email: antluba@mail.ru
Rússia, Svobodnyi pr. 79, Krasnoyarsk, 660041
N. Galiakhmetova
Institute of Nonferrous Metals and Materials Science
Email: antluba@mail.ru
Rússia, Svobodnyi pr. 79, Krasnoyarsk, 660041
V. Denisov
Institute of Nonferrous Metals and Materials Science
Email: antluba@mail.ru
Rússia, Svobodnyi pr. 79, Krasnoyarsk, 660041
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