Structural and Magnetic Properties of a BaFe12– xScxO19 Substituted Hexagonal Ferrite


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Abstract

Abstract—We have studied the effect of Sc3+ substitution for Fe3+ ions on the magnetic properties and crystal structure of BaFe12– xScxO19 hexaferrites. Based on Mössbauer spectroscopy data, we have assessed the distribution of scandium ions over sublattices and their effect on magnetic characteristics of the materials. The specific magnetization and coercive force of the ferrites have been shown to depend on the location and concentration of scandium ions in the crystal structure. The hexaferrite with x > 0.6 has been found to have a noncollinear magnetic structure.

About the authors

A. Yu. Mironovich

Moscow Institute of Steel and Alloys (National University of Science and Technology)

Email: trukhanov86@mail.ru
Russian Federation, Leninskii pr. 4, Moscow, 119991

S. V. Trukhanov

Scientific–Practical Materials Research Centre, Belarussian Academy of Sciences

Author for correspondence.
Email: trukhanov86@mail.ru
Belarus, vul. Brovki 19, Minsk, 220072

A. V. Trukhanov

Moscow Institute of Steel and Alloys (National University of Science and Technology); Scientific–Practical Materials Research Centre, Belarussian Academy of Sciences

Email: trukhanov86@mail.ru
Russian Federation, Leninskii pr. 4, Moscow, 119991; vul. Brovki 19, Minsk, 220072

V. V. Korovushkin

Moscow Institute of Steel and Alloys (National University of Science and Technology)

Email: trukhanov86@mail.ru
Russian Federation, Leninskii pr. 4, Moscow, 119991

M. N. Shipko

Lenin State Power University

Email: trukhanov86@mail.ru
Russian Federation, Rabfakovskaya ul. 34, Ivanovo, 153003

V. G. Kostishin

Moscow Institute of Steel and Alloys (National University of Science and Technology)

Email: trukhanov86@mail.ru
Russian Federation, Leninskii pr. 4, Moscow, 119991

I. M. Isaev

Moscow Institute of Steel and Alloys (National University of Science and Technology)

Email: trukhanov86@mail.ru
Russian Federation, Leninskii pr. 4, Moscow, 119991

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