Chemical Vapor Transport Growth of ZrSe2 Crystals Using Cl2 as a Transport Agent


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Abstract

A process has been proposed for ZrSe2 crystal growth with the use of ZrOCl2 as a transport agent source. The crystals thus grown have been characterized by X-ray diffraction. It has been shown that, unlike in the case of vanadium and molybdenum diselenides, the use of zirconium chloride causes no increase in crystal size. A mechanism of the chemical vapor transport process involved is proposed.

About the authors

K. S. Nikonov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: NikonovK.S@yandex.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

M. N. Brekhovskikh

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: NikonovK.S@yandex.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

T. K. Menshchikova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: NikonovK.S@yandex.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

V. A. Fedorov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: NikonovK.S@yandex.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

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