Interaction of the RNi1 –xSix (R = Dy, Gd; x = 0.05, 0.02) Compounds with Hydrogen


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Abstract

This paper reports the synthesis of RNi1 –xSix-based (R = Dy, Gd; x = 0.05, 0.02) intermetallic hydrides. The amount of absorbed hydrogen in the hydride phases is three to four atoms per formula unit. According to X-ray diffraction data, the synthesized hydrides have a crystal lattice with the FeB structure (sp. gr. Pnma, no. 62) at R = Dy and the CrB structure (sp. gr. Cmcm, no. 63) at R = Gd.

About the authors

S. A. Lushnikov

Moscow State University

Author for correspondence.
Email: lushnikov@hydride.chem.msu.ru
Russian Federation, Moscow, 119991

E. A. Movlaev

Moscow State University

Email: lushnikov@hydride.chem.msu.ru
Russian Federation, Moscow, 119991

V. N. Verbetsky

Moscow State University

Email: lushnikov@hydride.chem.msu.ru
Russian Federation, Moscow, 119991

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