High-Temperature Raman Scattering Study of the Li2O–B2O3–MoO3 System: I. Detailed Comparison of the Structures of Molten Lithium and Potassium Molybdates


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Abstract

The structure and polymerization behavior of molybdenum–oxygen groups in molten lithium and potassium molybdates with different alkali-metal oxide to molybdenum oxide ratios have been studied by high-temperature Raman spectroscopy. The results are analyzed in comparison with the structural units of pure molybdenum oxide.

About the authors

A. A. Sobol

Prokhorov General Physics Institute

Email: shukshinve@lst.gpi.ru
Russian Federation, ul. Vavilova 38, Moscow, 119991

V. E. Shukshin

Prokhorov General Physics Institute

Author for correspondence.
Email: shukshinve@lst.gpi.ru
Russian Federation, ul. Vavilova 38, Moscow, 119991

V. I. Lukanin

Prokhorov General Physics Institute

Email: shukshinve@lst.gpi.ru
Russian Federation, ul. Vavilova 38, Moscow, 119991

L. V. Moiseeva

Prokhorov General Physics Institute; Kurnakov Institute of General and Inorganic Chemistry

Email: shukshinve@lst.gpi.ru
Russian Federation, ul. Vavilova 38, Moscow, 119991; Leninskii pr. 31, Moscow, 119991

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