Email this article Effect of Precursor Mixture Composition on the Phase Composition and Electrical Transport Properties of Cu1.85ZnSnS4 and Cu1.5Zn1.15Sn0.85S4 Kesterite Solid Solutions Prepared in Molten KI
- Authors: Gapanovich M.V.1, Agapkin M.D.1, Odin I.N.2, Rakitin V.V.1, Sedlovets D.M.3, Kolesnikova A.M.1, Novikov G.F.1
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Affiliations:
- Institute of Problems of Chemical Physics
- Faculty of Chemistry
- Institute of Microelectronics Technology and High-Purity Materials
- Issue: Vol 54, No 8 (2018)
- Pages: 760-766
- Section: Article
- URL: https://journals.rcsi.science/0020-1685/article/view/158498
- DOI: https://doi.org/10.1134/S002016851808006X
- ID: 158498
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Abstract
We have studied the effect of precursor mixture composition on the phase composition and electrical transport properties of Cu1.85ZnSnS4 and Cu1.5Zn1.15Sn0.85S4 solid solutions with the kesterite structure, prepared by reacting binary sulfides and sulfur in molten KI, and found conditions for the synthesis of Cu1.85ZnSnS4 and Cu1.5Zn1.15Sn0.85S4 solid solutions free from inclusions of impurity phases. The Cu1.5Zn1.15Sn0.85S4 and Cu1.85ZnSnS4 solid solutions have been shown to be p-type semiconductors.
About the authors
M. V. Gapanovich
Institute of Problems of Chemical Physics
Email: i.n.odin@mail.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432
M. D. Agapkin
Institute of Problems of Chemical Physics
Email: i.n.odin@mail.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432
I. N. Odin
Faculty of Chemistry
Author for correspondence.
Email: i.n.odin@mail.ru
Russian Federation, Moscow, 119991
V. V. Rakitin
Institute of Problems of Chemical Physics
Email: i.n.odin@mail.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432
D. M. Sedlovets
Institute of Microelectronics Technology and High-Purity Materials
Email: i.n.odin@mail.ru
Russian Federation, Institutskaya ul. 6, Chernogolovka, Moscow oblast, 142432
A. M. Kolesnikova
Institute of Problems of Chemical Physics
Email: i.n.odin@mail.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432
G. F. Novikov
Institute of Problems of Chemical Physics
Email: i.n.odin@mail.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432
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