Resonance Excitation of Photoluminescence in an Aqueous Uranyl Chloride Solution

Abstract

We have measured photoluminescence spectra of an aqueous uranyl chloride solution under excitation by various light sources: semiconductor light-emitting diodes and cw laser. The excitation wavelength lay within a resonance absorption band of uranyl chloride, which ensured photoluminescence detection at exposure times of 10^–3 s using an extremely small volume of the substance (10^–9 cm³). The photoluminescence spectra were measured using a small minispectrometer, which allowed us to analyze the spectra in the range 200–1000 nm.