Synthesis of Fine-Particle Bismuth Orthogermanate in a NaCl/KCl Melt


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Abstract

We have developed a process for the synthesis of fine bismuth orthogermanate, Bi4Ge3O12 (BGO), powders in a NaCl/KCl melt and examined the effect of synthesis conditions on the phase composition and morphology of the powders. Our results demonstrate that the synthesized materials compare well in scintillation performance with single-crystal BGO: their scintillation efficiency is 90% relative to single-crystal BGO, with a decay time of 300 ns.

About the authors

O. M. Gaitko

Kurnakov Institute of General and Inorganic Chemistry

Author for correspondence.
Email: olenka-gajtko@yandex.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

V. O. Veselova

Kurnakov Institute of General and Inorganic Chemistry; Mendeleev University of Chemical Technology

Email: olenka-gajtko@yandex.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991; Miusskaya pl. 9, Moscow, 125047

V. D. Volodin

Vernadsky Institute of Geochemistry and Analytical Chemistry

Email: olenka-gajtko@yandex.ru
Russian Federation, ul. Kosygina 19, Moscow, 119991

A. V. Egorysheva

Kurnakov Institute of General and Inorganic Chemistry

Email: olenka-gajtko@yandex.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

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