Synthesis and High-Temperature Heat Capacity of Sm2Ge2O7 and Eu2Ge2O7


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The Sm2Ge2O7 and Eu2Ge2O7 germanates have been prepared by solid-state reactions via multistep firing of stoichiometric mixtures of Sm2O3 (Eu2O3) and GeO2 in air at temperatures from 1273 to 1473 K. The molar heat capacity of the samarium and europium germanates has been determined by differential scanning calorimetry in the range 350–1000 K and the Cp(T) data have been used to evaluate their thermodynamic properties.

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L. Denisova

Institute of Nonferrous Metals and Materials Science

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Email: antluba@mail.ru
俄罗斯联邦, Svobodnyi pr. 79, Krasnoyarsk, 660041

L. Irtyugo

Institute of Nonferrous Metals and Materials Science

Email: antluba@mail.ru
俄罗斯联邦, Svobodnyi pr. 79, Krasnoyarsk, 660041

Yu. Kargin

Baikov Institute of Metallurgy and Materials Science

Email: antluba@mail.ru
俄罗斯联邦, Leninskii pr. 49, Moscow, 119991

V. Beletskii

Institute of Nonferrous Metals and Materials Science

Email: antluba@mail.ru
俄罗斯联邦, Svobodnyi pr. 79, Krasnoyarsk, 660041

N. Belousova

Institute of Nonferrous Metals and Materials Science

Email: antluba@mail.ru
俄罗斯联邦, Svobodnyi pr. 79, Krasnoyarsk, 660041

V. Denisov

Institute of Nonferrous Metals and Materials Science

Email: antluba@mail.ru
俄罗斯联邦, Svobodnyi pr. 79, Krasnoyarsk, 660041

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