Reactions of manganese oxides with sulfuric acid solutions studied by kinetic and electrochemical methods


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Abstract

Reactions of manganese oxides of various compositions with sulfuric acid solutions have been studied by kinetic and electrochemical methods. The surface composition of the manganese oxides has been shown to vary during the dissolution process. We present mathematical dependences of the dissolution rate on kinetic parameters of the electrolyte solution for the oxides of various compositions and interpret the behavior of the manganese oxide with various compositions during dissolution in sulfuric acid solutions of various concentrations.

About the authors

E. B. Godunov

Kurnakov Institute of General and Inorganic Chemistry; Moscow Polytechnic University

Author for correspondence.
Email: gen225@mail.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991; Bol’shaya Semenovskaya ul. 38, Moscow, 107023

A. D. Izotov

Kurnakov Institute of General and Inorganic Chemistry

Email: gen225@mail.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

I. G. Gorichev

Moscow Polytechnic University

Email: gen225@mail.ru
Russian Federation, Bol’shaya Semenovskaya ul. 38, Moscow, 107023

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