Email this article Synthesis and characterization of sodium and potassium uranates with the compositions Na2[(UO2)6O4(OH)6] · 8H2 and K2[(UO2)6O4(OH)6] · 8H2
- Authors: Nipruk O.V.1, Chernorukov G.N.1, Abrazheev R.V.1, Kostrova E.L.1
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Affiliations:
- Lobachevsky State University
- Issue: Vol 53, No 8 (2017)
- Pages: 816-819
- Section: Article
- URL: https://journals.rcsi.science/0020-1685/article/view/158270
- DOI: https://doi.org/10.1134/S0020168517080131
- ID: 158270
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Abstract
Sodium and potassium uranates with the compositions M2[(UO2)6O4(OH)6] · 8Н2 (M = Na, K) have been synthesized by reacting schoepite (UO3 · 2.25H2O) with aqueous sodium hydroxide and potassium hydroxide solutions (pH 10–12) under hydrothermal conditions at 100°C for 15 days. Chemical analysis, X-ray diffraction, IR spectroscopy, and thermogravimetry data demonstrate that these compounds are perfect compositional and crystallographic analogs.
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About the authors
O. V. Nipruk
Lobachevsky State University
Author for correspondence.
Email: nipruk@yandex.ru
Russian Federation, pr. Gagarina 23a, Nizhny Novgorod, 603950
G. N. Chernorukov
Lobachevsky State University
Email: nipruk@yandex.ru
Russian Federation, pr. Gagarina 23a, Nizhny Novgorod, 603950
R. V. Abrazheev
Lobachevsky State University
Email: nipruk@yandex.ru
Russian Federation, pr. Gagarina 23a, Nizhny Novgorod, 603950
E. L. Kostrova
Lobachevsky State University
Email: nipruk@yandex.ru
Russian Federation, pr. Gagarina 23a, Nizhny Novgorod, 603950
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