Thermodynamic properties of p-Sm2Zr2O7


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Abstract

The isobaric heat capacity of p-Sm2Zr2O7 (pyrochlore phase) has been determined in the temperature range 10–1400 K using adiabatic, differential scanning, and relaxation calorimetry, and its enthalpy increment, entropy, and reduced Gibbs energy have been calculated with allowance for the contributions of its low-temperature magnetic transformations.

About the authors

P. G. Gagarin

Kurnakov Institute of General and Inorganic Chemistry

Email: guskov@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

A. V. Tyurin

Kurnakov Institute of General and Inorganic Chemistry

Email: guskov@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

V. N. Guskov

Kurnakov Institute of General and Inorganic Chemistry

Author for correspondence.
Email: guskov@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

A. V. Khoroshilov

Kurnakov Institute of General and Inorganic Chemistry

Email: guskov@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

G. E. Nikiforova

Kurnakov Institute of General and Inorganic Chemistry

Email: guskov@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

K. S. Gavrichev

Kurnakov Institute of General and Inorganic Chemistry

Email: guskov@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

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