Effect of magnesium on the performance characteristics of ZnS:Cu,Mn phosphors


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Abstract

We have studied the effect of magnesium added to the starting mixture as MgS or MgCl2 on the performance characteristics of synthesized ZnS:Cu,Mn phosphor powders. It has been shown that the incorporation of certain amounts of magnesium into the ZnS:Cu,Mn phosphor leads to an increase in photo- and electroluminescence brightness and is favorable for Mn incorporation into the structure of the phosphor. In particular, additional doping of a dc electroluminescent ZnS:Cu,Mn phosphor with 30 mol % Mg ensured not only a shift of its luminescence spectrum to shorter wavelengths, thereby extending the color range of light sources, but also a twofold increase in its brightness.

About the authors

K. A. Ogurtsov

St. Petersburg State Institute of Technology (Technical University)

Author for correspondence.
Email: ogurtsovka@yandex.ru
Russian Federation, Moskovskii pr. 26, St. Petersburg, 190013

M. M. Sychov

St. Petersburg State Institute of Technology (Technical University)

Email: ogurtsovka@yandex.ru
Russian Federation, Moskovskii pr. 26, St. Petersburg, 190013

V. V. Bakhmetyev

St. Petersburg State Institute of Technology (Technical University)

Email: ogurtsovka@yandex.ru
Russian Federation, Moskovskii pr. 26, St. Petersburg, 190013

V. N. Korobko

St. Petersburg State Institute of Technology (Technical University)

Email: ogurtsovka@yandex.ru
Russian Federation, Moskovskii pr. 26, St. Petersburg, 190013

A. I. Ponyaev

St. Petersburg State Institute of Technology (Technical University)

Email: ogurtsovka@yandex.ru
Russian Federation, Moskovskii pr. 26, St. Petersburg, 190013

F. I. Vysikailo

Technological Institute for Superhard and Novel Carbon Materials

Email: ogurtsovka@yandex.ru
Russian Federation, Tsentral’naya ul. 7a, Troitsk (Moscow), 142190

V. V. Belyaev

Moscow Oblast State University

Email: ogurtsovka@yandex.ru
Russian Federation, ul. Radio 10a, Moscow, 105005

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