Kinetics of germanium tetrachloride reduction with hydrogen in the presence of pyrolytic tungsten

Abstract

Pyrolytic tungsten coatings have been produced on the surface of ash microspheres under steady-state conditions using tungsten hexacarbonyl as a precursor. The nanostructured composites thus obtained were characterized by X-ray diffraction and scanning electron microscopy. We have studied the kinetics of the catalytic reduction of germanium tetrachloride with hydrogen in the temperature range 423–973 K in the presence of the composites as catalysts and determined the reaction order and activation energy for the catalytic reduction of germanium tetrachloride with hydrogen.