Unique hyper-kagome atomic order in the noncentrosymmetric structure of Na3Ir3O8


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The formation of a unique hyper-kagome atomic order in the structure of the ordered spinel phase Na3Ir3O8 has been analyzed in terms of the Landau theory of phase transitions. We have identified a critical six-component order parameter generating a phase transformation of the spinel parent phase to ordered P4132 (P4332) spinel-like enantiomorphs and examined the structural mechanism behind the development of hyper-kagome order and the detailed crystal chemistry of Na3Ir3O8.

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M. Talanov

Research Institute of Physics

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Email: mvtalanov@sfedu.ru
俄罗斯联邦, pr. Stachki 194, Rostov-on-Don, 344090

V. Shirokov

Southern Scientific Center; Platov State Polytechnic University

Email: mvtalanov@sfedu.ru
俄罗斯联邦, pr. Chekhova 41, Rostov-on-Don, 344006; ul. Prosveshcheniya 132, Novocherkassk, Rostov oblast, 346428

V. Talanov

Platov State Polytechnic University

Email: mvtalanov@sfedu.ru
俄罗斯联邦, ul. Prosveshcheniya 132, Novocherkassk, Rostov oblast, 346428

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