Heat capacity of the MVO4 (M = Al, Ga, In, Tl) orthovanadates


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Abstract

The heat capacity of InVO4 has been determined by differential scanning calorimetry in the temperature range 339–1089 K. The experimental Cp(T) data have been used to evaluate the thermodynamic functions of indium orthovanadate: enthalpy increment H°(T)–H°(339 K), entropy change S°(T)–S°(339 K), and reduced Gibbs energy Ф°(Т). The specific heats of GaVO4 and TlVO4 have been evaluated.

About the authors

L. T. Denisova

Institute of Nonferrous Metals and Materials Science

Author for correspondence.
Email: antluba@mail.ru
Russian Federation, Svobodnyi pr. 79, Krasnoyarsk, 660041

Yu. F. Kargin

Baikov Institute of Metallurgy and Materials Science

Email: antluba@mail.ru
Russian Federation, Leninskii pr. 49, Moscow, 119991

L. G. Chumilina

Institute of Nonferrous Metals and Materials Science

Email: antluba@mail.ru
Russian Federation, Svobodnyi pr. 79, Krasnoyarsk, 660041

V. M. Denisov

Institute of Nonferrous Metals and Materials Science

Email: antluba@mail.ru
Russian Federation, Svobodnyi pr. 79, Krasnoyarsk, 660041

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