High-pressure synthesis of H2Ta2O6 · H2O with a defect pyrochlore structure
- Authors: Zibro I.P.1, Filonenko V.P.1, Nikishina E.E.2, Lebedeva E.N.2, Drobot D.V.2
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Affiliations:
- Vereshchagin Institute of High-Pressure Physics
- Lomonosov State University of Fine Chemical Technologies
- Issue: Vol 52, No 1 (2016)
- Pages: 38-43
- Section: Article
- URL: https://journals.rcsi.science/0020-1685/article/view/157127
- DOI: https://doi.org/10.1134/S0020168515120158
- ID: 157127
Cite item
Abstract
Using high-pressure heat treatment of amorphous low-hydrated tantalum hydroxide of composition TaO0.5–2.0(OH)4–1 · 1.0–2.5H2O at p = 5.0 GPa and t = 600–750°C, we obtained a mixture of two phases: H2Ta2O6 · H2O with a defect pyrochlore structure (sp. gr. Fd3m, a = 10.5956(1) Å, Z = 8, V = 1189.53(3) Å3) and TT-Ta2O5 (δ) (α-UO3 structure, sp. gr. P3 m1, a = 3.6368(2) Å, c = 3.8943(5) Å, Z = 1, V = 44.61 Å3). The X-ray diffraction data for these compounds were analyzed by the Rietveld method. The agreement factors obtained are RF = 0.0541 for H2Ta2O6 · H2O and RF = 0.0885 for TT-Ta2O5. These phases are assumed to form an intergrowth structure along certain crystallographic planes. We have proposed a mechanism of intergrowth structure formation in the [111] direction of the pyrochlore structure and in the [001] direction of TT-Ta2O5.
About the authors
I. P. Zibro
Vereshchagin Institute of High-Pressure Physics
Email: filv@hppi.troitsk.ru
Russian Federation, Kaluzhskoe sh. 14, Troitsk, Moscow, 142190
V. P. Filonenko
Vereshchagin Institute of High-Pressure Physics
Author for correspondence.
Email: filv@hppi.troitsk.ru
Russian Federation, Kaluzhskoe sh. 14, Troitsk, Moscow, 142190
E. E. Nikishina
Lomonosov State University of Fine Chemical Technologies
Email: filv@hppi.troitsk.ru
Russian Federation, pr. Vernadskogo 86, Moscow, 119571
E. N. Lebedeva
Lomonosov State University of Fine Chemical Technologies
Email: filv@hppi.troitsk.ru
Russian Federation, pr. Vernadskogo 86, Moscow, 119571
D. V. Drobot
Lomonosov State University of Fine Chemical Technologies
Email: filv@hppi.troitsk.ru
Russian Federation, pr. Vernadskogo 86, Moscow, 119571
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