High-pressure synthesis of H2Ta2O6 · H2O with a defect pyrochlore structure


Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

Using high-pressure heat treatment of amorphous low-hydrated tantalum hydroxide of composition TaO0.5–2.0(OH)4–1 · 1.0–2.5H2O at p = 5.0 GPa and t = 600–750°C, we obtained a mixture of two phases: H2Ta2O6 · H2O with a defect pyrochlore structure (sp. gr. Fd3m, a = 10.5956(1) Å, Z = 8, V = 1189.53(3) Å3) and TT-Ta2O5 (δ) (α-UO3 structure, sp. gr. P3 m1, a = 3.6368(2) Å, c = 3.8943(5) Å, Z = 1, V = 44.61 Å3). The X-ray diffraction data for these compounds were analyzed by the Rietveld method. The agreement factors obtained are RF = 0.0541 for H2Ta2O6 · H2O and RF = 0.0885 for TT-Ta2O5. These phases are assumed to form an intergrowth structure along certain crystallographic planes. We have proposed a mechanism of intergrowth structure formation in the [111] direction of the pyrochlore structure and in the [001] direction of TT-Ta2O5.

About the authors

I. P. Zibro

Vereshchagin Institute of High-Pressure Physics

Email: filv@hppi.troitsk.ru
Russian Federation, Kaluzhskoe sh. 14, Troitsk, Moscow, 142190

V. P. Filonenko

Vereshchagin Institute of High-Pressure Physics

Author for correspondence.
Email: filv@hppi.troitsk.ru
Russian Federation, Kaluzhskoe sh. 14, Troitsk, Moscow, 142190

E. E. Nikishina

Lomonosov State University of Fine Chemical Technologies

Email: filv@hppi.troitsk.ru
Russian Federation, pr. Vernadskogo 86, Moscow, 119571

E. N. Lebedeva

Lomonosov State University of Fine Chemical Technologies

Email: filv@hppi.troitsk.ru
Russian Federation, pr. Vernadskogo 86, Moscow, 119571

D. V. Drobot

Lomonosov State University of Fine Chemical Technologies

Email: filv@hppi.troitsk.ru
Russian Federation, pr. Vernadskogo 86, Moscow, 119571

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2016 Pleiades Publishing, Ltd.