Vol 65, No 6 (2023)

A generalization of unpublished and published data since 1985 on biogeochemical, hydrogeochemical, geochemical, mineralogical studies and soil geochemistry at uranium deposits of the Khiagda ore field in the Vitim uranium ore district made it possible to reveal a genetic relation of deep cold carbonated hydrocarbonate–magnesium groundwater containing dissolved hydrocarbons (HCs) to uranium mineralization and ore preservation. The through penetration of epigenetic HCs was traced from the disintegration zone of basement granitoids through overlying sedimentary ore-bearing and volcanosedimentary rocks up to overlying fractured basalts. The assemblage of clarified rocks–HCs–siderites–uranium phosphates U(IV) was commonly found. Carbonated hydrocarbonate–magnesium groundwater and anomalous HC contents in soils can be additional criteria for identifying the Vitim-type uranium deposits in the Trans-Baikal region.

Polymineral aggregates of rounded shapes (“nodules”) composed of native and sulfide minerals of Cu, Ni, Fe, Ag, and other elements from vein magnetite–calcite–chrysotile rocks with jewelry demantoid in the Korkodinskoe hypermafic massif are described. A common feature of the six identified types of native sulfide nodules, composed of native copper, heazlewoodite, pentlandite, cuprite, and other native sulfide minerals, is their spheroidal shape, which makes them similar to individual grains of other gangue minerals (calcite, magnetite, etc.). In heazlewoodite–pentlandite nodules, specific symplectites of mercuric silver and nickel copper in heazlewoodite, as well as awaruite in Co–pentlandite, were found. The matching set of ore minerals in the host serpentinite vein mass (native copper, mercuric silver, heazlewoodite, pentlandite, awaruite) and nodules from the vein material indicates their genetic connection and the conjugation of demantoid mineralization with the evolving processes of serpentinization. It was established that the nodules formed at temperatures below 380°C under reducing conditions at very low sulfur fugacity values (10–17–10–27 bar) and oxygen (10–30 bar at 200°C to 10–21 bar at 350°C). For heazlewoodite–pentlandite nodules, such conditions persisted throughout the entire time of their formation, while, for other nodules, the reducing conditions of early parageneses were replaced by oxidative conditions in late parageneses, which is recorded by the replacement of native copper with cuprite. It is assumed that the features of the morphology and structure of native sulfide nodules and the presence of symplectite intergrowths of ore minerals in them are associated with specific conditions created during the decompression of the crust-mantle mixture rising to the surface in the fault zone. The source of the metals was a deep, high-temperature fluid interacting with mafic and ultramafic rocks under reducing conditions at a low water-to-rock ratio.

In the Malo-Botuobinsky, Sredne-Markhinsky, and Ygyattinsky diamond-bearing areas of the Western Yakutian kimberlite province, the prerequisites and signs of scandium deposits in ancient weathering crusts overlying Lower Paleozoic rocks and associated with zones of ancient reservoir and soil oxidation. According to X-ray fluorescence and ICP MS analyses, in the Nakyn kimberlite field of the Sredne-Markhinsky diamond-bearing region, promising ore occurrences and scandium concentration halos have been established in clay deposits of redeposited weathering crusts of the Dyakhtar Formation of Late Triassic–Early Jurassic age. They are confined to the erosional surface of Lower Paleozoic carbonate rocks and Middle Paleozoic traps, with monzonite porphyries and kimberlites cutting through them, covered on top by a sedimentary cover of Jurassic terrigenous deposits. Concentration anomalies of scandium in clays of the Dyakhtar Formation are localized mainly in deluvial clay deposits of paleowatersheds and gravitate to the intersections of tectonic disturbances. The depth of their occurrence does not exceed 100 m, which is quite favorable for the extraction of scandium by borehole in situ leaching. Concentrations of scandium were detected at one of the sites before 262 g/t in Late Triassic weathering crust, including material from a Middle Paleozoic gabbro dike, as well as overlying colluvial clays of the Dyakhtar formations with a maximum of 462 g/t.