NEON AS A CRITERION FOR NOBLE GAS DISTRIBUTION BETWEEN GAS ACCUMULATIONS AND EDGEWATER

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Abstract

The dependence of the isotopic composition of Ne on the partial pressure of Ne, N2 and the ratio of N2 /Ne is analyzed for the first time. The scale of the influence of groundwater on the content and isotopic composition of noble gases in CO2, N2 and CH4 gas reservoirs is also estimated. It is shown that the partial pressure of Ne in gas accumulations increases in the range: CO2 – CH4 – N2. The CO2 gas accumulations are characterized by the mantle isotopic composition of neon, and the N2 gas accumulations are dominated by a mixture of atmospheric and crustal neon (20Ne/22Ne is in the range of 8.9–10.2; 21Ne/22Ne 0.040–0.083). The initial concentrations and isotopic composition of Ne and, obviously, other noble gases depend on the conditions of formation of the gas phase that enters the reservoir. Subsequently, the partial pressure of Ne in the CO2 and CH4 gas accumulations increases, and the partial pressure of Ne in the N2 gas accumulations decreases, presumably due to gas exchange with groundwater. A model of gas exchange between gas accumulations and groundwater is proposed, which makes it possible to estimate the distribution of noble gases between them: (1) CO2 enters reservoirs with negligibly low (0.008 Pa) partial pressures of mantle Ne. Therefore, the admixture of Ne from groundwater can reach 90 % in them; (2) On the contrary, N2 deposits have an atmospheric isotopic composition of Ne with the addition of a nucleogenic (crustal) component and a partial pressure higher than in the atmosphere. The ancient Cl–Ca brines at the reservoir pressure below 300 bar are the most likely source of this N2 gas phase; (3) The isotopic composition of Ne in CH4 accumulations corresponds to the microbial methane which is formed in near–surface conditions (the environment enriched in atmospheric gases), while thermogenic methane is formed at greater depths. Probably, major part of the Ne and N2 in the thermogenic CH4 accumulations are the result of the gas exchange with Cl–Ca brines. In general, the isotopic composition of Ne in CH4 accumulations reflect the mixing of microbial and thermogenic CH4 on migration routes to the surface.

About the authors

V. V. Tikhomirov

Saint Petersburg State University, Institute of Earth Sciences

10th Line V.O., 33-35, St. Petersburg, 199178 Russia

V. G. Tikhomirova

Saint Petersburg State University, Institute of Earth Sciences

10th Line V.O., 33-35, St. Petersburg, 199178 Russia

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