Thermal and Thermochemical Study of Thaumasite

Yu. D. Gritsenko; Гриценко Ю. Д.; M. F. Vigasina; Вигасина М. Ф.; L. V. Mel’chakova; Мельчакова Л. В.; L. P. Ogorodova; Огородова Л. П.; D. A. Ksenofontov; Ксенофонтов Д. А.; S. K. Dedushenko; Дедушенко С. К.

doi:10.31857/S0016752523110043

Thermal and Thermochemical Study of Thaumasite

Authors: Gritsenko Y.D.¹^,2, Vigasina M.F.¹, Mel’chakova L.V.¹, Ogorodova L.P.¹, Ksenofontov D.A.¹, Dedushenko S.K.³
Affiliations:
1. Faculty of Geology, Lomonosov Moscow State University, 119991, Moscow, Russia
2. Fersman Mineralogical Museum, Russian Academy of Sciences, 119692, Moscow, Russia
3. NUST MISIS, 119049, Moscow, Russia
Issue: Vol 68, No 12 (2023)
Pages: 1273-1283
Section: Articles
URL: https://journals.rcsi.science/0016-7525/article/view/233641
DOI: https://doi.org/10.31857/S0016752523110043
EDN: https://elibrary.ru/WRJTKE
ID: 233641

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Abstract
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Abstract

A sample of natural thaumasite Ca3.0Si(OH)6(CO3)0.9(SO4)1.1·12.3H2O (N’Chwaning mine, Kalahari manganese ore field, South Africa) was studied by powder X-ray diffraction, infrared absorption and Raman spectroscopy, thermal analysis, and microcalorimetry. The process of thermal transformation of thaumasite was studied using the results of FTIR and Raman spectroscopy. The enthalpy of formation from elements ΔfH0(298.15 K) = −8816 ± 30 kJ/mol was determined by high-temperature melt solution calorimetry. The value of the absolute entropy was estimated, and the enthalpy and Gibbs energy of formation of thaumasite of theoretical composition were calculated: 945.4 ± 1.8 J/(mol K), −8699 ± 30 kJ/mol, −7577 ± 30 kJ/mol, respectively.

Keywords

thaumasite, thermal analysis, FTIR, Raman, Calvet microcalorimetry, enthalpy of formation, Gibbs energy

References

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