SODALITE: SPECTROSCOPIC AND THERMOCHEMICAL INVESTIGATIONS

M. F. Vigasina; Вигасина М. Ф.; S. V, Vyatkin; Вяткин С. В.; L. P. Ogorodova; Огородова Л. П.; V. V. Maltsev; Мальцев В. В.; L. V. Melchakova; Мельчакова Л. В.; Yu. D. Gritsenko; Гриценко Ю. Д.; E. N. Eremina; Ерёмина Е. Н.

doi:10.31857/S0016752523060043

SODALITE: SPECTROSCOPIC AND THERMOCHEMICAL INVESTIGATIONS

Autores: Vigasina M.¹, Vyatkin S.¹, Ogorodova L.¹, Maltsev V.¹, Melchakova L.¹, Gritsenko Y.¹^,2, Eremina E.¹^,3
Afiliações:
1. Geological Faculty, Lomonosov Moscow State University
2. Fersman Mineralogical Museum, Russian Academy of Sciences
3. Kola Science Centre, Laboratory of Arctic Mineralogy and Materials Science, Russian Academy of Sciences
Edição: Volume 68, Nº 7 (2023)
Páginas: 720-729
Seção: Articles
URL: https://journals.rcsi.science/0016-7525/article/view/134824
DOI: https://doi.org/10.31857/S0016752523060043
EDN: https://elibrary.ru/EOJLPP
ID: 134824

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Resumo

Two sodalite samples (sample I is Na8Al6Si6O24Cl2⋅0.4H2O from the Kovdor alkaline ultramafic massif with carbonatites in the Murmansk region, Russia, and sample II is Na8Al6Si6O24Cl2⋅0.2H2O from the Bayan Kol nepheline syenite and miaskite massif in the Republic of Tyva) were studied by thermal and electron-microprobe analyses, powder X-ray diffraction, photoluminescence, and by IR, Raman, and ESR spectroscopy. Solution melt calorimetry was applied to determine the enthalpy of formation from elements for water-bearing sodalite samples: −13536 ± 10 (I) and −13503 ± 19 (II) kJ/mol. The enthalpy of formation of sodalite of the theoretical composition Na8Al6Si6O24Cl2 was evaluated at ΔfH0(298.15 K) = −13446 ± 11 kJ/mol. The data obtained on the enthalpy of formation of sodalite and literature data on its S0(298.15 K) were used to calculate the standard Gibbs energies of formation of anhydrous and of water-bearing sodalite.

Palavras-chave

X-ray powder diffraction, electron-microprobe analysis, photoluminescence, IR spectroscopy, ESR spectroscopy. Raman spectroscopy, thermal analysis, Calvet microcaloriometry, enthalpy, Gibbs energy, sodalite

Bibliografia

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