Thermodynamic Properties of Coquimbite and Aluminocoquimbite

Yu. D. Gritsenko; Гриценко Ю. Д.; L. P. Ogorodova; Огородова Л. П.; M. F. Vigasina; Вигасина М. Ф.; D. A. Kosova; Косова Д. А.; S. K. Dedushenko; Дедушенко С. К.; L. V. Melchakova; Мельчакова Л. В.; D. A. Ksenofontov; Ксенофонтов Д. А.

doi:10.31857/S0016752523050059

Thermodynamic Properties of Coquimbite and Aluminocoquimbite

Autores: Gritsenko Y.¹^,2, Ogorodova L.¹, Vigasina M.¹, Kosova D.³, Dedushenko S.⁴, Melchakova L.¹, Ksenofontov D.¹
Afiliações:
1. Geological Faculty, Lomonosov Moscow State University
2. Fersman Mineralogical Museum, Russian Academy of Sciences
3. Chemical Faculty, Lomonosov Moscow State University
4. NUST MISIS
Edição: Volume 68, Nº 6 (2023)
Páginas: 622-628
Seção: Articles
URL: https://journals.rcsi.science/0016-7525/article/view/134816
DOI: https://doi.org/10.31857/S0016752523050059
EDN: https://elibrary.ru/ELQGOT
ID: 134816

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Resumo

Coquimbite AlFe3+3[SO4]6(H2O)12⋅6H2O (sample from the Javier Mine, Peru) has been studied by thermal and electron microprobe analysis, X-ray powder diffraction, Raman spectroscopy, and Mössbauer spectroscopy. The enthalpy of formation of the coquimbite from elements ∆fH0(298.15 K) = −11 118 ± 40 kJ/mol was determined by the method of solution calorimetry in melt of lead borate 2PbO∙B2O3 on a Setaram (France) Calvet microcalorimeter. The value of its absolute entropy S0(298.15 K) = 1248.3 ± 3.0 J/(mol K) was estimated, the entropy of formation ∆fS0(298.15 K) = − 5714.0 ±3.0 J/mol K), and the Gibbs energy of formation from elements ∆fG0(298.15 K) = −9411 ± 40 kJ/mol were calculated. The values of the enthalpy and Gibbs energy of formation of aluminocoquimbite Al2Fe3+2[SO4]6(H2O)12⋅6H2O from elements were estimated at −11 540 ± 29 and −9830 ± 29 kJ/mol, respectively.

Palavras-chave

coquimbite, X-ray powder diffraction, Raman spectroscopy, Mössbauer spectroscopy, thermal analysis, Calvet microcalorimetry, enthalpy, entropy, Gibbs energy

Bibliografia

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