Vol 47, No 5 (2016)
- Year: 2016
- Articles: 18
- URL: https://journals.rcsi.science/0015-0541/issue/view/14564
Article
Bottle Wastes − to Textile Yarns
Abstract
Treatment of polyethylene terephthalate (PET) bottle wastes is one of the ways of utilizing solid household garbage accumulated in dumps worldwide, including in Russia. A large part of the utilized PET bottles in the form of washed flakes is processed into staple fibre for nonwoven materials and fillers. The German company BBE offered equipment and technology that allow conversion of PET flakes into a product akin to a standard primary polymer, which makes it possible to cast polyester textile filaments of the desired quality and thereby not only to expand the sales market, but also to solve important ecological and economic problems.
Macrostructure of Polyacrylonitrile Nanofibers Produced by Electrospinning
Abstract
The surface properties of polyacrylonitrile nanofibers were studied using capillary condensation of N2 and scanning electron microscopy. The macrostructures of polyacrylonitrile fibers produced by electrospinning and coagulation were compared. The composition of polyacrylonitrile nanofibers was characterized by the fiber diameter.
Wetting of Carbon Fibers by Coal-Tar Pitch Melts
Abstract
Wetting of carbon fibers by model liquids (water and octane) and melts of pure coal-tar pitch and that with myristic acid added as a surfactant was studied by the Wilhelmy method. It was shown that the contact angles of the carbon fibers by the pitch that were calculated using wetting data for the model liquids agreed with the directly measured values. Addition of myristic acid equalized the polar and dispersive components of the pitch-melt surface free energy and improved the wettability.
Structural, Adsorption, and Mass-Transfer Properties of Polycaproamide
Abstract
from a comprehensive investigation of the structural and adsorption properties of fibrous polycaproamide were presented. An analysis of them allowed polycaproamide to be assessed as a desiccant. Mechanistic features of the interaction of polycaproamide with water were examined. The adsorption required to design a drying process was determined. The mass-transfer coefficient was analyzed as a function of moisture content and drying temperature.
Features of Hydrogen Bonds in Aromatic Polyamides Containing Benzimidazole Groups According to Ab Initio Quantum Chemical Calculations
Abstract
Results of the analysis of the influence of hydrogen bonds in aromatic polyamides on technological processing methods for the production of heavy-duty aramid yarns CVM, Rusar, and Ruslan are presented herein. Quantum-chemical calculations of model fragments in conjunction with vibrational spectra in the infrared range have shown that, depending on the hydrogen bonds between the benzimidazole groups, “self-orientation” processes emerge caused by the increase in energy of the hydrogen bonds in the aramid yarns and fibers. This explains the uniquely high values describing mechanical properties of the yarns and their performance characteristics in cloths, plastics, and spool products.
Hierarchy of Structural Associates of Catalytically Active Sites on an Acrylonitrile-Based Polymeric Fibrous Carrier
Abstract
The characteristic features of the structural hierarchy of the formation of iron-containing catalytic sites on polymeric carriers based on modified polyacrylonitrile and copolymer of acrylonitrile with methyl acrylate were determined using optical and X-ray spectroscopy. It has been shown that some of the short ring structures that appear in the creation of a polydentate ligand lose their ability to coordinate the metal and may not be included in the composition of catalytically active particles entering the complex formation reaction.
Estimating the Distribution of Different Types of Fibers in Cross Sections of Two-Component Hybrid Yarn
Abstract
The fiber distribution is estimated in cross sections of the structure of two-component hybrid yarn made from para-aramid and polyamide yarns. Two types of structures of hybrid yarns were studied, with different processing parameters. The basic parameters of the fiber distribution in cross sections of the yarns are determined.
Development of Textile Materials for Protection from Microwave Radiation Using Bismuth Nanoparticles
Abstract
The synthesis of nanoparticles of bismuth was performed, which consisted of chemical reduction from Bi(NO3)3 solution. Optimal parameters for the reduction of bismuth to zero valence metal state, and its application to the fabric were developed. The modified fabric subjected to microwave radiation yields a decrease in the radiation dose. The material can be used in radioprotective clothing with enhanced partial protection, which includes overalls, helmet, gloves, and shoe covers made from radio-reflective materials.
Change in Cross Sectional Shape for Hollow Filament During Winding
Abstract
Methods for obtaining hollow-fiber membranes are limited (due to the small diameter) compared with methods for obtaining other membranes. An important problem in obtaining hollow filaments by any method is development of devices for take-up of the semi-permeable hollow fibers. This is due to the specific characteristics of hollow filaments (the presence of an internal cavity). During winding of hollow filaments, loss of stability can occur under the action of radial pressure arising in the take-up from winding tension. We will consider the critical pressure to be the lowest external pressure at which the initial shape of the hollow filament cannot be recovered when the external pressure is relieved. In this work, we have analyzed the conditions for loss of stability in hollow filaments when they are obtained on equipment for building packages.
Evaluating Models for Predicting the Air Permeability of Needle-Punched Nonwovens
Abstract
An analysis is made of effective models that have been proposed for predicting the air permeability of needle-punched nonwovens in accordance with the requirements of the Russian standard. An approach that entails constructing models with a single structural parameter is suggested. The parameter can be thickness, surface density, volumetric density, or the space factor. The given approach precludes obtaining models with one correction factor. Models constructed with two correction factors make it possible to predict air permeability for certain values of the structural parameters. The optimum model uses surface density as the structural parameter.
Chemistry and Technology of Chemical Fibres
Structure-Formation Features in Ultrathin Fibers of Poly(3-Hydroxybutyrate) Modified with Nanoparticles
Abstract
Supramolecular structure formation of poly(3-hydroxybutyrate) ultrathin fibers prepared by electrospinning and the influence of low concentrations of silicon and TiO2 nanoparticles on the structure, physicomechanical and sorption properties, and resistance to thermal destruction and thermoand photo-oxidative destruction of non-woven fibrous material based on these fibers were studied. It was found that nanoparticles promoted the formation of thinner fibers with enhanced physicomechanical parameters and a structure that was more resistant to thermal and thermo- and photo-oxidative destruction and had a positive effect on the growth dynamics of mesenchymal stem cells.
Fibre Composite Materials
Polypropylene Threads Modified by Iron-Containing Nanoparticles Stabilized in Polyethylene
Abstract
The production and properties of polypropylene threads modified by small amounts of iron-containing nanoparticles were studied. The nanoparticles were stabilized during the synthesis by immobilizing them in a low-density polyethylene matrix. The structure of the modified threads was examined. The strength, friction coefficients, surface electrical resistance, and antimicrobial properties of the threads were evaluated.
Materials Science
Evaluation of the Industrial Processability of High-Strength and High-Modulus Yarns in Weaving, Taking into Account Abrasion Resistance
Abstract
We evaluate the industrial processability of high-strength and high-modulus multifilament yarns in weaving. The procedure for evaluating the processability of a yarn is based on determining the abrasion resistance of the yarns under conditions simulating loom operation. We determine the basic physical and mechanical properties of different types of multifilament yarns, including their abrasion resistance, which affect the processability of the yarns in weaving, letting us predict the weaving conditions.
Research Methods
Analysis of the Main Methods of Monitoring the Blending of Natural and Chemical Fibers
Abstract
A classification is presented for well-known methods and equipment used to evaluate the composition and uniformity of blends of natural and chemical fibers. A visual method, a photometric method, and a method based on differences between the physicochemical properties of the components being blended are analyzed. Aspects of the use of these methods are also discussed.
Machines and Equipment
Improving the Effectiveness of Filter Regeneration by Pulse Scavenging
Abstract
Scientific research and experimental-design work are performed to improve the effectiveness of regenerating bag and cassette filters by reverse pulse scavenging. It is recommended that the velocity and flow rate of the compressed air used for scavenging be chosen as the regime parameters, depending on the physico-mechanical properties of the dust that is being captured. A method of calculating the grouped distribution of collectors is proposed to uniformly distribute the compressed air among the scavenging nozzles. It is also recommended that swirl nozzles be used to equalize the pressure pulses along the filter elements.
Process Control Systems
Comparing the Use of the Simoyu Method and the Ident Program in Matlab for Parametric Identification of the Tension-Stabilizing Process in the Winding of a Steamed Filament
Abstract
To study the dynamics of a control object, it is necessary to obtain its transfer function or construct a model of it. The process of identification was carried out by Simoyu’s method and by means of the program Ident, which is built into the system Matlab. The input and output variables of the object were observed by performing an active experiment. A stepped control action was applied and a recording was made of the resulting output data, which was in the form of a transient response. To eliminate experimental errors, the tabulated data was smoothed with the use of a cubic spline after normalization. Double smoothing was performed with a step of 0.04 sec and then a step of 0.02 sec to record the volume of data.