Hierarchy of Structural Associates of Catalytically Active Sites on an Acrylonitrile-Based Polymeric Fibrous Carrier

Abstract

The characteristic features of the structural hierarchy of the formation of iron-containing catalytic sites on polymeric carriers based on modified polyacrylonitrile and copolymer of acrylonitrile with methyl acrylate were determined using optical and X-ray spectroscopy. It has been shown that some of the short ring structures that appear in the creation of a polydentate ligand lose their ability to coordinate the metal and may not be included in the composition of catalytically active particles entering the complex formation reaction.