Unusual platinum complexes in the gas phase


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Resumo

Previously unknown cationic platinum complexes Pt(C5H4N)(C5H5N)+ and Pt(C5H4N)+, where platinum atom forms an unusual three-membered metallacycle with a deprotonated pyridine molecule, were detected in the gas phase by mass spectrometry and structurally characterized by DFT quantum-chemical calculations.

Sobre autores

A. Markov

Kurnakov Institute of General and Inorganic Chemistry

Autor responsável pela correspondência
Email: wahr36@gmail.com
Rússia, Leninskii pr. 31, Moscow, 119991

I. Yakushev

Kurnakov Institute of General and Inorganic Chemistry

Email: wahr36@gmail.com
Rússia, Leninskii pr. 31, Moscow, 119991

A. Churakov

Kurnakov Institute of General and Inorganic Chemistry

Email: wahr36@gmail.com
Rússia, Leninskii pr. 31, Moscow, 119991

I. Stolyarov

Kurnakov Institute of General and Inorganic Chemistry

Email: wahr36@gmail.com
Rússia, Leninskii pr. 31, Moscow, 119991

N. Cherkashina

Kurnakov Institute of General and Inorganic Chemistry

Email: wahr36@gmail.com
Rússia, Leninskii pr. 31, Moscow, 119991

A. Kornev

Institute of Problems in Chemical Physics

Email: wahr36@gmail.com
Rússia, pr. Semenova 1, Chernogolovka, Moscow oblast, 142432

M. Vargaftik

Kurnakov Institute of General and Inorganic Chemistry

Email: wahr36@gmail.com
Rússia, Leninskii pr. 31, Moscow, 119991

A. Gekhman

Kurnakov Institute of General and Inorganic Chemistry

Email: wahr36@gmail.com
Rússia, Leninskii pr. 31, Moscow, 119991

I. Moiseev

Kurnakov Institute of General and Inorganic Chemistry

Email: wahr36@gmail.com
Rússia, Leninskii pr. 31, Moscow, 119991

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