Email this article Unusual platinum complexes in the gas phase
- Authors: Markov A.A.1, Yakushev I.A.1, Churakov A.V.1, Stolyarov I.P.1, Cherkashina N.V.1, Kornev A.B.2, Vargaftik M.N.1, Gekhman A.E.1, Moiseev I.I.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- Institute of Problems in Chemical Physics
- Issue: Vol 468, No 1 (2016)
- Pages: 72-75
- Section: Physical Chemistry
- URL: https://journals.rcsi.science/0012-5016/article/view/153535
- DOI: https://doi.org/10.1134/S0012501616050031
- ID: 153535
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Abstract
Previously unknown cationic platinum complexes Pt(C5H4N)(C5H5N)+ and Pt(C5H4N)+, where platinum atom forms an unusual three-membered metallacycle with a deprotonated pyridine molecule, were detected in the gas phase by mass spectrometry and structurally characterized by DFT quantum-chemical calculations.
About the authors
A. A. Markov
Kurnakov Institute of General and Inorganic Chemistry
Author for correspondence.
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 119991
I. A. Yakushev
Kurnakov Institute of General and Inorganic Chemistry
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 119991
A. V. Churakov
Kurnakov Institute of General and Inorganic Chemistry
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 119991
I. P. Stolyarov
Kurnakov Institute of General and Inorganic Chemistry
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 119991
N. V. Cherkashina
Kurnakov Institute of General and Inorganic Chemistry
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 119991
A. B. Kornev
Institute of Problems in Chemical Physics
Email: wahr36@gmail.com
Russian Federation, pr. Semenova 1, Chernogolovka, Moscow oblast, 142432
M. N. Vargaftik
Kurnakov Institute of General and Inorganic Chemistry
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 119991
A. E. Gekhman
Kurnakov Institute of General and Inorganic Chemistry
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 119991
I. I. Moiseev
Kurnakov Institute of General and Inorganic Chemistry
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 119991
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