Mono- and Di(dechloromethylthioylation) of Dichloromethylarenes with S-Methyl Diethylthiophosphinate
- 作者: Gazizov M.1, Valieva G.1, Ivanova S.1, Khairullin R.1, Kirillina Y.1, Antipin I.2
-
隶属关系:
- Kazan State Technological University
- Kazan State University
- 期: 卷 489, 编号 1 (2019)
- 页面: 257-260
- 栏目: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154529
- DOI: https://doi.org/10.1134/S0012500819110016
- ID: 154529
如何引用文章
详细
The attack of the thiol sulfur atom (P–SMe) on the methine carbon as the main route of the new reaction of dichloromethylarenes with S-methyl diethylthiophosphinate has been predicted and experimentally confirmed on the basis of the electronic structure of the S-alkyl esters of P(IV) acids. The processes of the mono- and di(dechloromethylthioylation) of dichloromethyl group have been realized. A new approach to the synthesis of the arenecarbaldehyde dimethyl dithioacetals has been developed avoiding the use of gaseous highly toxic methyl mercaptan.
作者简介
M. Gazizov
Kazan State Technological University
编辑信件的主要联系方式.
Email: mukattisg@mail.ru
俄罗斯联邦, Kazan,
420015
G. Valieva
Kazan State Technological University
Email: mukattisg@mail.ru
俄罗斯联邦, Kazan,
420015
S. Ivanova
Kazan State Technological University
Email: mukattisg@mail.ru
俄罗斯联邦, Kazan,
420015
R. Khairullin
Kazan State Technological University
Email: mukattisg@mail.ru
俄罗斯联邦, Kazan,
420015
Yu. Kirillina
Kazan State Technological University
Email: mukattisg@mail.ru
俄罗斯联邦, Kazan,
420015
I. Antipin
Kazan State University
Email: mukattisg@mail.ru
俄罗斯联邦, Kazan, 420008