Mono- and Di(dechloromethylthioylation) of Dichloromethylarenes with S-Methyl Diethylthiophosphinate
- Авторы: Gazizov M.1, Valieva G.1, Ivanova S.1, Khairullin R.1, Kirillina Y.1, Antipin I.2
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Учреждения:
- Kazan State Technological University
- Kazan State University
- Выпуск: Том 489, № 1 (2019)
- Страницы: 257-260
- Раздел: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154529
- DOI: https://doi.org/10.1134/S0012500819110016
- ID: 154529
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Аннотация
The attack of the thiol sulfur atom (P–SMe) on the methine carbon as the main route of the new reaction of dichloromethylarenes with S-methyl diethylthiophosphinate has been predicted and experimentally confirmed on the basis of the electronic structure of the S-alkyl esters of P(IV) acids. The processes of the mono- and di(dechloromethylthioylation) of dichloromethyl group have been realized. A new approach to the synthesis of the arenecarbaldehyde dimethyl dithioacetals has been developed avoiding the use of gaseous highly toxic methyl mercaptan.
Об авторах
M. Gazizov
Kazan State Technological University
Автор, ответственный за переписку.
Email: mukattisg@mail.ru
Россия, Kazan,
420015
G. Valieva
Kazan State Technological University
Email: mukattisg@mail.ru
Россия, Kazan,
420015
S. Ivanova
Kazan State Technological University
Email: mukattisg@mail.ru
Россия, Kazan,
420015
R. Khairullin
Kazan State Technological University
Email: mukattisg@mail.ru
Россия, Kazan,
420015
Yu. Kirillina
Kazan State Technological University
Email: mukattisg@mail.ru
Россия, Kazan,
420015
I. Antipin
Kazan State University
Email: mukattisg@mail.ru
Россия, Kazan, 420008