Mono- and Di(dechloromethylthioylation) of Dichloromethylarenes with S-Methyl Diethylthiophosphinate
- Authors: Gazizov M.B.1, Valieva G.D.1, Ivanova S.Y.1, Khairullin R.A.1, Kirillina Y.S.1, Antipin I.S.2
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Affiliations:
- Kazan State Technological University
- Kazan State University
- Issue: Vol 489, No 1 (2019)
- Pages: 257-260
- Section: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154529
- DOI: https://doi.org/10.1134/S0012500819110016
- ID: 154529
Cite item
Abstract
The attack of the thiol sulfur atom (P–SMe) on the methine carbon as the main route of the new reaction of dichloromethylarenes with S-methyl diethylthiophosphinate has been predicted and experimentally confirmed on the basis of the electronic structure of the S-alkyl esters of P(IV) acids. The processes of the mono- and di(dechloromethylthioylation) of dichloromethyl group have been realized. A new approach to the synthesis of the arenecarbaldehyde dimethyl dithioacetals has been developed avoiding the use of gaseous highly toxic methyl mercaptan.
About the authors
M. B. Gazizov
Kazan State Technological University
Author for correspondence.
Email: mukattisg@mail.ru
Russian Federation, Kazan,
420015
G. D. Valieva
Kazan State Technological University
Email: mukattisg@mail.ru
Russian Federation, Kazan,
420015
S. Yu. Ivanova
Kazan State Technological University
Email: mukattisg@mail.ru
Russian Federation, Kazan,
420015
R. A. Khairullin
Kazan State Technological University
Email: mukattisg@mail.ru
Russian Federation, Kazan,
420015
Yu. S. Kirillina
Kazan State Technological University
Email: mukattisg@mail.ru
Russian Federation, Kazan,
420015
I. S. Antipin
Kazan State University
Email: mukattisg@mail.ru
Russian Federation, Kazan, 420008