New One-Pot Synthesis of Polysubstituted Benzofurans and Benzo-1,4-dioxines
- Autores: Sakhabutdinova G.1, Raskil’dina G.1, Zlotskii S.1, Sultanova R.1,2
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Afiliações:
- Ufa State Petroleum Technological University
- Ufa Institute of Chemistry
- Edição: Volume 482, Nº 2 (2018)
- Páginas: 233-236
- Seção: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154305
- DOI: https://doi.org/10.1134/S0012500818100051
- ID: 154305
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Resumo
It has been revealed that the copper(II) triflate catalyzed reaction of ethyl-2-diazo-3-oxobutanoate with phenols followed by cyclization of the intermediate enol in the presence of polyphosphoric acid is a simple and efficient method of synthesis of polysubstituted benzofurans. The use of pyrocatechol leads to the corresponding substituted 1,4-benzodioxine-2-carboxylates as major products.
Sobre autores
G. Sakhabutdinova
Ufa State Petroleum Technological University
Email: sultanova_rm@anrb.ru
Rússia, Ufa, Bashkortostan, 450105
G. Raskil’dina
Ufa State Petroleum Technological University
Email: sultanova_rm@anrb.ru
Rússia, Ufa, Bashkortostan, 450105
S. Zlotskii
Ufa State Petroleum Technological University
Email: sultanova_rm@anrb.ru
Rússia, Ufa, Bashkortostan, 450105
R. Sultanova
Ufa State Petroleum Technological University; Ufa Institute of Chemistry
Autor responsável pela correspondência
Email: sultanova_rm@anrb.ru
Rússia, Ufa, Bashkortostan, 450105; Ufa, Bashkortostan, 450054