New Photochromic Salt Spiropyrans of Indoline Series
- Authors: Lapshina L.S.1, Minkin V.I.2, Aldoshin S.M.3, Pugachev A.D.2, Lukyanova M.B.2, Tkachev V.V.3, Lukyanov B.S.2,1, Makarova N.I.2, Shilov G.V.3, Rostovtseva I.A.2
-
Affiliations:
- Don State Technical University
- Research Institute of Physical and Organic Chemistry, Southern Federal University
- Institute of Problems in Chemical Physics, Russian Academy of Sciences
- Issue: Vol 484, No 2 (2019)
- Pages: 58-63
- Section: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154383
- DOI: https://doi.org/10.1134/S0012500819020113
- ID: 154383
Cite item
Abstract
Synthesis, structure study, and photochromic properties of new salt spiropyrans of indoline series containing chlorine and bromine atoms in the 6'-position of the 2H-chromene moiety have been reported. The structure of the obtained compounds has been confirmed by 1H NMR spectroscopy and X-ray diffraction analysis. The compounds are photochromic; the long-wavelength absorption maximum for photoinduced isomer shows a considerable hypsochromic shift, while the lifetime increases considerably as compared with the fluorine-containing analog.
About the authors
L. S. Lapshina
Don State Technical University
Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don,
344000
V. I. Minkin
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090
S. M. Aldoshin
Institute of Problems in Chemical Physics, Russian Academy of Sciences
Email: lab811@ipoc.sfedu.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
A. D. Pugachev
Research Institute of Physical and Organic Chemistry, Southern Federal University
Author for correspondence.
Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090
M. B. Lukyanova
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090
V. V. Tkachev
Institute of Problems in Chemical Physics, Russian Academy of Sciences
Email: lab811@ipoc.sfedu.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
B. S. Lukyanov
Research Institute of Physical and Organic Chemistry, Southern Federal University; Don State Technical University
Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090; Rostov-on-Don,
344000
N. I. Makarova
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090
G. V. Shilov
Institute of Problems in Chemical Physics, Russian Academy of Sciences
Email: lab811@ipoc.sfedu.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
I. A. Rostovtseva
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090