New Photochromic Salt Spiropyran with Benzyl Substituent
- Authors: Luk’yanova M.B.1, Pugachev A.D.1, Tkachev V.V.2, Luk’yanov B.S.1,3, Shilov G.V.2, Kozlenko A.S.1, Rostovtseva I.A.1, Minkin V.I.1, Aldoshin S.M.2
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Affiliations:
- Research Institute of Physical and Organic Chemistry
- Institute of Problems in Chemical Physics
- Don State Technical University
- Issue: Vol 482, No 2 (2018)
- Pages: 220-224
- Section: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154297
- DOI: https://doi.org/10.1134/S0012500818100026
- ID: 154297
Cite item
Abstract
A new salt spiropyran of indoline series containing benzyl substituent in the 8'-position of the [2H]-chromene moiety of the molecule has been synthesized and studied. The structure of the obtained compound has been confirmed by methods 1H NMR and IR spectroscopy. The study of spectral characteristics and photochromic behavior of the target compound has shown that growing of its single crystal resulted in destruction on account of hydrolysis in acetonitrile. The 1H NMR spectra of the initial salt spiropyran and product of hydrolysis have been compared.
About the authors
M. B. Luk’yanova
Research Institute of Physical and Organic Chemistry
Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090
A. D. Pugachev
Research Institute of Physical and Organic Chemistry
Author for correspondence.
Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090
V. V. Tkachev
Institute of Problems in Chemical Physics
Email: lab811@ipoc.sfedu.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
B. S. Luk’yanov
Research Institute of Physical and Organic Chemistry; Don State Technical University
Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090; Rostov-on-Don, 344007
G. V. Shilov
Institute of Problems in Chemical Physics
Email: lab811@ipoc.sfedu.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
A. S. Kozlenko
Research Institute of Physical and Organic Chemistry
Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090
I. A. Rostovtseva
Research Institute of Physical and Organic Chemistry
Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090
V. I. Minkin
Research Institute of Physical and Organic Chemistry
Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090
S. M. Aldoshin
Institute of Problems in Chemical Physics
Email: lab811@ipoc.sfedu.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432