New Photochromic Salt Spiropyran with Benzyl Substituent


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Abstract

A new salt spiropyran of indoline series containing benzyl substituent in the 8'-position of the [2H]-chromene moiety of the molecule has been synthesized and studied. The structure of the obtained compound has been confirmed by methods 1H NMR and IR spectroscopy. The study of spectral characteristics and photochromic behavior of the target compound has shown that growing of its single crystal resulted in destruction on account of hydrolysis in acetonitrile. The 1H NMR spectra of the initial salt spiropyran and product of hydrolysis have been compared.

About the authors

M. B. Luk’yanova

Research Institute of Physical and Organic Chemistry

Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090

A. D. Pugachev

Research Institute of Physical and Organic Chemistry

Author for correspondence.
Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090

V. V. Tkachev

Institute of Problems in Chemical Physics

Email: lab811@ipoc.sfedu.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

B. S. Luk’yanov

Research Institute of Physical and Organic Chemistry; Don State Technical University

Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090; Rostov-on-Don, 344007

G. V. Shilov

Institute of Problems in Chemical Physics

Email: lab811@ipoc.sfedu.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

A. S. Kozlenko

Research Institute of Physical and Organic Chemistry

Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090

I. A. Rostovtseva

Research Institute of Physical and Organic Chemistry

Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090

V. I. Minkin

Research Institute of Physical and Organic Chemistry

Email: lab811@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don, 344090

S. M. Aldoshin

Institute of Problems in Chemical Physics

Email: lab811@ipoc.sfedu.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432


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