Garnet Solid Solution (Y1 – xBix)3Fe2.5Ga2.5O12


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Abstract

Samples of composition (Y1–xBix)3Fe2.5Ga2.5O12 (0 ≤ х ≤1), synthesized by the polyvinyl alcohol gel combustion method, have been studied by X-ray diffraction. It has been shown that the homogeneity range of the solid solution persists up to the composition Y1.5Bi1.5Fe2.5Ga2.5O12. This allows to consider gallium- substituted bismuth yttrium ferrites with an equimolar Fe: Ga ratio as stable materials for possible use in magnetooptics.

About the authors

M. N. Smirnova

Kurnakov Institute of General and Inorganic Chemistry

Author for correspondence.
Email: smirnova_macha1989@mail.ru
Russian Federation, Moscow, 119991

G. D. Nipan

Kurnakov Institute of General and Inorganic Chemistry

Email: smirnova_macha1989@mail.ru
Russian Federation, Moscow, 119991

G. E. Nikiforova

Kurnakov Institute of General and Inorganic Chemistry

Email: smirnova_macha1989@mail.ru
Russian Federation, Moscow, 119991

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