Interaction of [В10H10]2– and [В12H12]2– with nitro compounds
- Authors: Kubasov A.S.1, Matveev E.Y.2, Turyshev E.S.3, Polyakova I.N.1, Zhizhin K.Y.1,2, Kuznetsov N.T.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- Moscow Technological University
- Mendeleev Uviversity of Chemical Technology of Russia
- Issue: Vol 477, No 1 (2017)
- Pages: 257-260
- Section: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154103
- DOI: https://doi.org/10.1134/S0012500817110088
- ID: 154103
Cite item
Abstract
The interaction of the [B10H10]2– and [B12H12]2– anions with aliphatic and aromatic nitro compounds (RNO2, where R = Et, n-Pr, i-Pr, tert-Bu, Ph) has been studied under irradiation with visible and UV light. It has been shown that, depending on the reaction conditions, both mono- and disubstituted nitro-closo-decaborates can be selectively obtained in yields up to 50%.
About the authors
A. S. Kubasov
Kurnakov Institute of General and Inorganic Chemistry
Author for correspondence.
Email: fobosax@mail.ru
Russian Federation, Moscow, 119991
E. Yu. Matveev
Moscow Technological University
Author for correspondence.
Email: cat1983@yandex.ru
Russian Federation, Moscow, 119571
E. S. Turyshev
Mendeleev Uviversity of Chemical Technology of Russia
Email: cat1983@yandex.ru
Russian Federation, Moscow, 125047
I. N. Polyakova
Kurnakov Institute of General and Inorganic Chemistry
Email: cat1983@yandex.ru
Russian Federation, Moscow, 119991
K. Yu. Zhizhin
Kurnakov Institute of General and Inorganic Chemistry; Moscow Technological University
Email: cat1983@yandex.ru
Russian Federation, Moscow, 119991; Moscow, 119571
N. T. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry
Email: cat1983@yandex.ru
Russian Federation, Moscow, 119991