Interaction of [В 10 H 10 ] 2–  and [В 12 H 12 ] 2–  with nitro compounds

A. S. Kubasov; E. Yu. Matveev; E. S. Turyshev; I. N. Polyakova; K. Yu. Zhizhin; N. T. Kuznetsov

doi:10.1134/S0012500817110088

Interaction of [В₁₀H₁₀]^2– and [В₁₂H₁₂]^2– with nitro compounds

作者: Kubasov A.S.¹, Matveev E.Y.², Turyshev E.S.³, Polyakova I.N.¹, Zhizhin K.Y.¹^,2, Kuznetsov N.T.¹
隶属关系:
1. Kurnakov Institute of General and Inorganic Chemistry
2. Moscow Technological University
3. Mendeleev Uviversity of Chemical Technology of Russia
期: 卷 477, 编号 1 (2017)
页面: 257-260
栏目: Chemistry
URL: https://journals.rcsi.science/0012-5008/article/view/154103
DOI: https://doi.org/10.1134/S0012500817110088
ID: 154103

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The interaction of the [B₁₀H₁₀]^2– and [B₁₂H₁₂]^2– anions with aliphatic and aromatic nitro compounds (RNO₂, where R = Et, n-Pr, i-Pr, tert-Bu, Ph) has been studied under irradiation with visible and UV light. It has been shown that, depending on the reaction conditions, both mono- and disubstituted nitro-closo-decaborates can be selectively obtained in yields up to 50%.