Stereolithographic Fabrication of Alumina Ceramics from Aluminum Chloride-Containing Polymerizable Precursors

D. S. Larionov; Ларионов Д. С.; P. V. Evdokimov; Евдокимов П. В.; A. V. Garshev; Гаршев А. В.; D. A. Kozlov; Козлов Д. А.; V. I. Putlyaev; Путляев В. И.

doi:10.31857/S0002337X23020100

Stereolithographic Fabrication of Alumina Ceramics from Aluminum Chloride-Containing Polymerizable Precursors

Authors: Larionov D.S.¹, Evdokimov P.V.¹^,2, Garshev A.V.¹^,2, Kozlov D.A.¹, Putlyaev V.I.¹^,2
Affiliations:
1. Faculty of Materials Science, Moscow State University, 119991, Moscow, Russia
2. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia
Issue: Vol 59, No 2 (2023)
Pages: 216-226
Section: Articles
URL: https://journals.rcsi.science/0002-337X/article/view/140138
DOI: https://doi.org/10.31857/S0002337X23020100
EDN: https://elibrary.ru/YDPISK
ID: 140138

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

An approach has been proposed for preparing polymerizable precursors to alpha-alumina and aluminum oxynitride ceramics and using them in stereolithographic fabrication of aluminum-containing ceramics. With allowance for their homogeneity (optical transmission), photopolymerizability, and weight loss during thermolysis, three precursors based on aluminum chlorides (anhydrous and hexahydrate) and a basic aluminum chloride were chosen for characterization. We analyzed the behavior of the precursors during firing in an ammonia atmosphere for the preparation of oxynitride ceramics and during firing in air for the preparation of alpha-alumina ceramics from homogeneous precursors. Stereolithographic 3D printing of alpha-alumina ceramics was tested, in particular with the use of the proposed precursors in the form of photopolymerizable binders allowing the fraction of alumina in photosuspensions to be increased.

Keywords

ceramics, alumina, aluminum oxynitrides, polymerizable precursor, alumoxanes, stereolithographic 3D printing

References

Zocca A., Colombo P., Gomes C.M., Günster J. Additive Manufacturing of Ceramics: Issues, Potentialities, and Opportunities // J. Am. Ceram. Soc. 2015. V. 98. № 7. P. 1983–2001. https://doi.org/10.1111/jace.13700
Ievlev V.M., Putlyaev V.I., Safronova T.V., Evdokimov P.V. Additive Technologies for Making Highly Permeable Inorganic Materials with Tailored Morphological Architectonics for Medicine // Inorg. Mater. 2015. V. 51. № 13. P. 1295–1313. https://doi.org/10.1134/S0020168515130038
Colombo P., Mera G., Riedel R., Sorarù G.D. Polymer-Derived Ceramics: 40 Years of Research and Innovation in Advanced Ceramics // J. Am. Ceram. Soc. 2010. V. 93. № 7. P. 1805–1837. https://doi.org/10.1111/j.1551-2916.2010.03876.x
Liew L.A., Liu Y., Luo R., Cross T., An L., Bright V.M., Dunn M.L., Daily J.W., Raj R. Fabrication of SiCN MEMS by Photopolymerization of Preceramic Polymer // Sens. Actuators, A. 2002. V. 95. № 2–3. P. 120–134. https://doi.org/10.1109/MEMSYS.2002.984340
Heimann R.B. Silicon Nitride, a Close to Ideal Ceramic Material for Medical Application // Ceramics. 2021. V. 4. P. 208–223. https://doi.org/10.3390/ceramics4020016
Rey C., Combes C., Drouet C. Bioinert Ceramics: State-of-the-Art // Key Eng. Mater. 2017. V. 758. P. 3–13. doi: 10.4028/ href='www.scientific.net/KEM.758.3' target='_blank'>www.scientific.net/KEM.758.3
Eckel Z.C., Zhou C., Martin J.H., Jacobsen A.J., Carter W.B., Schaedler T.A. Additive Manufacturing Of Polymer-Derived Ceramics // Science. 2016. V. 351. № 6268. P. 58–62. https://doi.org/10.1126/science.aad2688
De Hazan Y., Penner D. SiC and SiOC Ceramic Articles Produced by Stereolithography of Acrylate Modified Polycarbosilane Systems // J. Eur. Ceram. Soc. 2017. V. 37. № 16. P. 5205–5212. https://doi.org/10.1016/j.jeurceramsoc.2017.03.021
Новаков И.А., Радченко Ф.С. Наноразмерные алюмоксановые частицы-прекурсоры органо-неорганических гибридных полимерных композиций // Изв. ВолгГТУ. 2013. № 4 (107). С. 5–20.
Стороженко П.А., Щербакова Г.И., Цирлин А.М., Муркина А.С., Варфоломеев М.С., Кузнецова М.Г., Полякова М.В., Трохаченкова О.П. Органоалкоксиалюмосиликаты и бескремнеземное связующее на их основе // Неорган. материалы. 2007. Т. 43. № 3. С. 373–382. https://doi.org/10.1134/S0002337X19100130
He J., Avnir D., Zhang L. Sol–Gel Derived Alumina Glass: Mechanistic Study of Its Structural Evolution // Acta Mater. 2019. V. 174 P. 418–426. https://doi.org/10.1016/j.actamat.2019.05.062
Baixia L., Yinkui L., Yi. L. Preparation of Aluminium Nitride from Organometallic/Polymeric Precursors // J. Mater. Chem. 1993. V. 3. № 2. P. 117–127. https://doi.org/10.1039/JM9930300117
Jensen J.A. Organoaluminum Precursor Polymers for Aluminum Nitride Ceramics // Inorganic and Organometallic Polymers II. ACS Symposium Series, Ch. 32. Washington, DC: Am. Chem. Soc., 1994. P. 428–439. https://doi.org/10.1021/bk-1994-0572.ch032
Naderi-beni B., Alizadeh A. Preparation of Single Phase AlON Powders Aided by the Nitridation of Sol-Gel-Derived Nanoparticles // Ceram. Int. 2019. V. 45. P. 7537–7543. https://doi.org/10.1016/j.ceramint.2019.01.047
Ивичева С.Н., Овсянников Н.А., Лысенков А.С., Климашин А.А., Каргин Ю.Ф. Синтез оксонитридоалюмосиликатов золь-гель методом // Журн. неорган. химии. 2020. Т. 65. № 12. С. 1614–1625. https://doi.org/10.1134/S0036023620120050
Орлов Н.К., Евдокимов П.В., Милькин П.А., Тихонов А.А., Тихонова С.А., Климашина Е.С., Зуев Д.М., Капитанова О.О., Путляев В.И. Синтез прекерамического прекурсора на основе органических солей алюминия для стереолитографической 3D-печати корундовой керамики // Перспективные материалы. 2021. № 4. С. 67–80. https://doi.org/10.30791/1028-978X-2021-4-67-80
Chase M.W. NIST–JANAF Thermochemical Tables, Fourth Edition // J. Phys. Chem. Ref. Data. Monograph 9. 1998. P. 1–1951.
Willems H.X., Hendrix M.M.R.M., Metselaar R., de With G. Thermodynamics of Alon I: Stability at Lower Temperatures // J. Eur. Ceram. Soc. 1992. V. 10. P. 327–337. https://doi.org/10.1016/0955-2219(92)90088-U
Corbin N.D. Aluminum Oxynitride Spinel: a Review // J. Eur. Ceram. Soc. 1989. V. 5. P. 143–154. https://doi.org/10.1016/0955-2219(89)90030-7
Kaufman L. Calculation of Quasibinary and Quasiternary Oxynitride Systems – III // Calphad. 1979. V. 3. P. 275–291.
Валеев Д.В., Лайнер Ю.А., Самохин А.В., Синайский М.А., Михайлова А.Б., Куцев С.В., Гольдберг М.А. Физико-химические исследования процесса термогидролиза хлорида алюминия // Перспективные материалы. 2016. № 1. С. 64–73. https://doi.org/10.1134/S2075113316050269
Tabary P., Servant C. Thermodynamic Reassessment of the AlN-A12O3 System // Calphad. 1999. V. 22. № 2. P. 179–201. https://doi.org/10.1016/S0364-5916(98)00023-6
Becher P. Microstructural Design of Toughened Ceramics // J. Am. Ceram. Soc. 1991. V. 74. № 2. P. 255–269. https://doi.org/10.1111/j.1151-2916.1991.tb06872.x