ELECTRODYNAMIC MODEL OF OXYGEN REDOX SORPTION BY METAL-CONTAINING NANOCOMPOSITES

T. A. Kravchenko; D. V. Konev; D. D. Vakhnin; A. V. Chumakova

doi:10.1134/S1995078019060090

ELECTRODYNAMIC MODEL OF OXYGEN REDOX SORPTION BY METAL-CONTAINING NANOCOMPOSITES

作者: Kravchenko T.A.¹, Konev D.V.², Vakhnin D.D.¹, Chumakova A.V.¹
隶属关系:
1. Voronezh State University
2. Institute of Problems of Chemical Physics, Russian Academy of Sciences
期: 卷 14, 编号 11-12 (2019)
页面: 523-530
栏目: Self-Assembled Structures and Nanoassemblies
URL: https://journals.rcsi.science/2635-1676/article/view/220871
DOI: https://doi.org/10.1134/S1995078019060090
ID: 220871

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详细

An electrodynamic model of the redox sorption of oxygen from water on metal-ion-exchange nanocomposites’ (NCs) granular layers is proposed. It features a simultaneous description of the oxygen reduction process along the electrochemical and chemical routes. Due to the inhomogeneous oxidation of metal nanoparticles by oxygen, the granular layer of the NC ohmic resistance, which varies in height and time, is taken into account. The adequacy of the model was tested on a copper-containing NC.