Electroconductive hydrophobic polymer composite materials based on oxidized carbon nanotubes modified with tetrafluoroethylene telomers


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Abstract

In this paper we describe a way to prepare hybrid functional polymer materials (HFPMs) based on epoxy binders that contain functionalized carbon nanotubes and a compatibilizer (Cherflon tetrafluoroethylene telomer). A micropattern has been found to form on the prepreg surface in the lack of external pressure that ensures high-level hydrophobicity (the wetting angle is 144.3°). We also offer a method for the formation of a hydrophobic pattern on a cured plastic surface (the wetting angle reaches 136° for water). The lateral and transverse specific volume resistances of the studied HFPM sample with respect to the reinforcer packing plane are 19 Ω cm and 6.7 × 102 Ω cm. A 0.68-mm-thick HFPM film was found to transmit ca. 1% and to reflect 75–80% of the incident electromagnetic power in the 27–34 GHz frequency range.

About the authors

E. N. Kablov

All-Russian Institute of Aircraft Materials

Author for correspondence.
Email: kompozity@inbox.ru
Russian Federation, Moscow, 105005

L. V. Solov’yanchik

All-Russian Institute of Aircraft Materials

Email: kompozity@inbox.ru
Russian Federation, Moscow, 105005

S. V. Kondrashov

All-Russian Institute of Aircraft Materials

Email: kompozity@inbox.ru
Russian Federation, Moscow, 105005

G. Yu. Yurkov

Baikov Institute of Metallurgy and Material Sciences

Email: kompozity@inbox.ru
Russian Federation, Moscow, 119991

V. M. Buznik

All-Russian Institute of Aircraft Materials

Email: kompozity@inbox.ru
Russian Federation, Moscow, 105005

P. P. Kushch

Institute of Chemical Physics Problems

Email: kompozity@inbox.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

G. A. Kichigina

Institute of Chemical Physics Problems

Email: kompozity@inbox.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

D. P. Kiryukhin

Institute of Chemical Physics Problems

Email: kompozity@inbox.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

T. P. D’yachkova

Tambov State Technical University

Email: kompozity@inbox.ru
Russian Federation, Tambov, 392000

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