Restructuring of the meso-methyl-substituted thiacarbocyanine aggregates in solution: Molecular nanomachines


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Abstract

Spontaneous transformation in the aqueous solution of the metal-complex J-aggregates of the meso-methyl-substituted thiacarbocyanine into the metal-complex H-aggregates is studied. It is concluded that the transformation of aggregates is connected with a change in the structure of their primary aggregates from the monomer packing of the “brickwork” type to packing of the “ladder” type.

About the authors

B. I. Shapiro

Moscow Technological University (Institute of Fine Chemical Technology)

Author for correspondence.
Email: bishapiro@mail.ru
Russian Federation, pr. Vernadskogo 86, Moscow, 119571

E. V. Manulik

Moscow Technological University (Institute of Fine Chemical Technology)

Email: bishapiro@mail.ru
Russian Federation, pr. Vernadskogo 86, Moscow, 119571

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