Effect of Modification with Cesium Acid Salt of Phosphotungstic Acid on the Properties of Membranes Based on Grafted Sulfonated Polystyrene


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Аннотация

The possibility of modification of ion-exchange membranes with high pore and channel volumes and the effect of doping on the membrane properties have been studied. Hybrid membranes based on sulfonated polystyrene grafted onto polymethylpentene and cesium acid phosphotungstate have been synthesized by the in situ method. It has been shown that modification of these membranes leads to an increase in conductivity to 34.8 mS/cm at 25°С in contact with water. The chloride anion transport numbers for the original and modified membranes are about 4%.

Авторлар туралы

I. Prikhno

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Institute of Problems of Chemical Physics, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: ivan_prikhno@mail.ru
Ресей, Moscow, 119991; Chernogolovka, Moscow oblast, 142432

A. Yaroslavtsev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: ivan_prikhno@mail.ru
Ресей, Moscow, 119991; Chernogolovka, Moscow oblast, 142432

D. Golubenko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: ivan_prikhno@mail.ru
Ресей, Moscow, 119991; Chernogolovka, Moscow oblast, 142432

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